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We introduce quantum Markov states (QMS) in a general tree graph , extending the Cayley tree’s case. We investigate the Markov property w.r.t. the finer structure of the considered tree. The main result of this paper concerns the diagonalizability of a locally faithful QMS on a UHF-algebra over the considered tree by means of a suitable conditional expectation into a maximal abelian subalgebra. Namely, we prove the existence of a Umegaki conditional expectation $\mathfrak E : \mathcal A_V \to \mathcal D_V$ Moreover, we clarify the Markovian structure of the associated classical measure on the spectrum of the diagonal algebra .

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