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We present a fine-structure entanglement classification under stochastic local operation and classical communication (SLOCC) for multiqubit pure states. To this end, we employ specific algebraic-geometry tools that are SLOCC invariants, secant varieties, to show that for -qubit systems there are entanglement families. By using another invariant, -multilinear ranks, each family can be further split into a finite number of subfamilies. Not only does this method facilitate the classification of multipartite entanglement, but it also turns out to be operationally meaningful as it quantifies entanglement as a resource.

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