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We present high spectral-resolution observations of comets 122P/de Vico and 153P/Ikeya-Zhang obtained with the Tull Coud'{e} spectrograph on the 2.7m Harlan J. Smith telescope of McDonald Observatory. We used these data to study the distribution of the lines of the C (Swan) bands. We show that the data are best represented with two rotational temperatures, with the lowest energy lines being at a relatively cool temperature and the higher energy lines being at a higher temperature. We discuss the implications of this two temperature distribution and suggest future work.

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