We consider (iced) quiver with potential associated to a Postnilov Diagram and prove the mutation of the quiver with potential is compatible with the geometric exchange of the Postnikov diagram . This ensures we may define a quiver with potential for a Grassmannian cluster algebra. We show such quiver with potential is always rigid (thus non-degenerate) and Jacobian-finite. And in fact, it is the unique non-degenerate (thus unique rigid) quiver with potential associated to the Grassmannian cluster algebra up to right-equivalence, by using a general result of Gei\ss-Labardini-Schr"oer. As an application, we verify that the auto-equivalence group of the generalized cluster category is isomorphic to the cluster automorphism group of the associated Grassmannian cluster algebra with trivial coefficients.

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