NbRhB crystallises in a chiral noncentrosymmetric structure and exhibits bulk type-II superconductivity below ~K. Here we show that the temperature dependence of the upper critical field deviates from the behaviour expected for both Werthamer-Helfand-Hohenberg and the Ginzburg-Landau models and that ~T exceeds the Pauli paramagnetic limit, ~T. We explore the reasons for this enhancement. Transverse-field muon spectroscopy measurements suggest that the superconducting gap is either -wave or -wave, and the pressure dependence of reveals the superconducting gap is primarily -wave in character. The magnetic penetration depth ~nm. Heat capacity measurements reveal the presence of a multigap -wave superconducting order parameter and moderate electron-phonon coupling.

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