The evolutionary paths taken by massive stars with $M \gtrsim 60 , _\odot$ remain substantially uncertain. They begin their lives as main sequence (MS) O-stars. Depending on their masses, rotation rates, and metallicities, they can then encounter a wide range of evolutionary states with an equally broad set of possible surface compositions and spectral classifications. We present a new grid of calculations for the evolution of such stars that covers a broad range in mass, M/M to , rotation rate, to , metallicity, to , and -element enhancement, to . We show that rotating stars undergo rotationally-induced dredge-up of nucleosynthetic products, mostly He and N, to their surfaces while still on the MS. Non-rotating metal-rich stars also reveal the products of nucleosynthesis on their surfaces because even modest amounts of mass loss expose their “fossil” convective cores: regions that are no longer convective, but which were part of the convective core at an early stage in the star’s evolution. Thus surface enhancement of He and N is expected for rotating stars at all metallicities, and for non-rotating stars if they are relatively metal-rich. We calculate a stellar atmosphere for a representative model from our grid, properly accounting for He- and N-enhancement, and show that the resulting spectrum provides a good match to observed WNL stars, strongly suggesting that the physical mechanisms we have identified are the ultimate cause of the WNL phase.

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