The classical transport of magnetic field and electron energy in a plasma requires the use of coefficients that depend on plasma ionization and magnetization . This paper explains these scalings through studying the electron velocities responsible for each transport process. Both electron-electron collisions and magnetization affect higher velocity electron populations preferentially, lowering the carrier velocities; transport carried by a high energy electron population is therefore more suppressed by both electron-electron collisions and magnetization than transport carried by lower velocities. Carrier Hall parameters are defined for each coefficient such that magnetization can be described independent of ionization. An analytic idealized coefficient with a single rigid carrier velocity reproduces many of the characteristics of the coefficients, in particular thermal conductivity, but overestimates plasma magnetization due to magnetization itself lowering the carrier velocity. A single moving carrier model improves agreement, but cannot describe the smoothness of the Righi-Leduc coefficient, which originates from being an average over a range of carrier velocities. This is the first paper in a 3-part series; the subsequent papers will extend the carrier picture to non-local heat-flux (paper 2) and non-local magnetic field evolution (paper 3).

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