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A high-precision measurement of the CsXe ground-to-ground-state electron-capture -value was performed using the ISOLTRAP mass spectrometer at ISOLDE/CERN. The novel PI-ICR technique allowed to reach a relative mass precision of . A mass resolving power exceeding was obtained in only s trapping time. Allowed electron-capture transitions with sub-keV or lower decay energies are of high interest for the direct determination of the mass. The new measurement improves the uncertainty on the ground-to-ground-state -value by a factor 25 precluding the CsXe pair as a feasible candidate for the direct determination of the mass.

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