Electrochemical properties of Na${}_{0.66}$V${}_4$O${}_{10}$ nanostructures as cathode material in rechargeable batteries for energy storage applications

We report the electrochemical performance of nanostructures of Na${}_{0.66}$V${}_4$O${}_{10}$ as cathode material for rechargeable batteries. The Rietveld refinement of room temperature x-ray diffraction pattern shows the monoclinic phase with C2/m space group. The cyclic voltammetry curves of prepared half-cells exhibit redox peaks at ~3.1 and 2.6~V, which are due to two-phase transition reaction between V${}^{5+\mathrm{/}4+}$ and can be assigned to the single step deintercalation/intercalation of Na-ion. We observe a good cycling stability with specific discharge capacity (measured vs. Na${}^{+}$/Na) between 80 ($\pm$2) and 30 ($\pm$2) mAh g${}^{-1}$ at a current density 3 and 50~mA g${}^{-1}$, respectively. The electrochemical performance of Na${}_{0.66}$V${}_4$O${}_{10}$ electrode was also tested with Li anode, which showed higher capacity, but decay faster than Na. Using density functional theory, we calculate the Na vacancy formation energies; 3.37~eV in the bulk of the material and 2.52~eV on the (100) surface, which underlines the importance of nanostructures.