We consider the initial value problem which determines the pathlines of a two-phase flow, i.e.\ is a given velocity field of the type with denoting the bulk phases of the two-phase fluid system under consideration. The bulk phases are separated by a moving and deforming interface . Since we allow for flows with phase change, these pathlines are allowed to cross or touch the interface. Imposing a kind of transversality condition at , which is intimately related to the mass balance in such systems, we show existence and uniqueness of absolutely continuous solutions of the above ODE in case the one-sided velocity fields $v^\pm:\overline{{\rm gr}(\Omega^\pm)}\to ^n(t,x)x$. Note that this is a necessary prerequisite for the existence of well-defined co-moving control volumes for two-phase flows, a basic concept for mathematical modeling of two-phase continua.

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