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We give a construction of the universal enveloping algebra of a given algebra, alternative to the already existing versions. As applications, we derive a higher homotopy algebras version of the classical Milnor-Moore theorem, proposing a new model for simply connected rational homotopy types, and uncovering a relationship between the higher order rational Whitehead products in homotopy groups and the Pontryagin-Massey products in the rational loop space homology algebra.

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