The concept of boundary values of holomorphic semigroups in a general Banach space is studied. As an application, we consider the Riemann-Liouville semigroup of integration operator in the little H"older spaces and prove that it admits a strongly continuous boundary group, which is the group of fractional integration of purely imaginary order. The corresponding result for the -spaces () has been known for some time, the case dating back to the monograph by Hille and Phillips. In the context of spaces, we establish the existence of the boundary group of the Hadamard fractional integration operators using semigroup methods. In the general framework, using a suitable spectral decomposition,we give a partial treatment of the inverse problem, namely: Which -groups are boundary values of some holomorphic semigroup of angle ?

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