An open question of fundamental importance in quantum thermodynamics is how to describe the statistics of work for initial state with quantum coherence. In this paper, work statistics is considered from a fully new perspective of “wave-particle” duality. Based on the generalized quantum work measurement, predictability of energy levels and effectiveness of coherence are defined, and they obey inequality , which is the fundamental tradeoff relations between the contributions of population and coherence to quantum work distribution. As an application, we consider a driven two-level system and discuss the condition of the bound of above tradeoff relation. These results shed light on the effects of quantum coherence in quantum thermodynamics.

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