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We study harmonic functions and Poisson boundaries for Borel probability measures on general (i.e., not necessarily locally compact) topological groups, and we prove that a second-countable topological group is amenable if and only if it admits a fully supported, regular Borel probability measure with trivial Poisson boundary. This generalizes work of Kaimanovich–Vershik and Rosenblatt, confirms a general topological version of Furstenberg’s conjecture, and entails a characterization of the amenability of isometry groups in terms of the Liouville property for induced actions. Moreover, our result has non-trivial consequences concerning Liouville actions of discrete groups on countable sets

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