Transition-metal perovskite oxides exhibit moderately correlated metallic phases, several of which exhibit a resistivity scaling up to temperatures far exceeding the regime where Fermi-liquid electron-electron scattering is expected to dominate. Some of these materials, such as SrMoO, also exhibit unexplained ultra-low room-temperature resistivity. We demonstrate that in SrMoO, SrWO, SrTaO, SrNbO, and SrVO electron-phonon scattering results in quadratic-scaling resistivity due to the shape of the Fermi surface and the thermal activation of optical phonons. We also reveal that the origin of the low resistivity of SrMoO is an overall low electron-phonon coupling strength, and identify SrWO and SrTaO as other possible low-resistivity oxides. Additionally, we find that the strength of electron-phonon coupling is sensitive to structural distortions, energies of optical phonons, and the treatment of electronic correlations. This suggests design principles for finding other ultra-high conductivity transition-metal oxides, and has significant implications for theoretical interpretation of direct-current resistivity in transition-metal oxides and beyond.

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