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For a scalar evolution equation the cohomology spaces vanishes for while the space is isomorphic to the space of variational operators. The cohomology space is also shown to be isomorphic to the space of symplectic operators for for which the equation is Hamiltonian. Third order scalar evolution equations admitting a first order symplectic (or variational) operator are characterized. The symplectic nature of the potential form of a bi-Hamiltonian evolution equation is also presented.

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