Consider the Schr"odinger operator in $^n, n\ge 3,V$ is a nonnegative potential satisfying a reverse H"older condition of the type \begin{equation*} \left( \frac{1}{|B|}\int_B V(y)^qdy\right)^{1/q}\le \frac{C}{|B|}\int_B V(y)dy, , q>n/2. \end{equation*} We define the class of measurable functions such that where is the critical radius function associated to . Let be the heat semigroup of . Given we denote by the set of functions which satisfy \begin{equation*} |\rho(\cdot)^{-\alpha}f(\cdot)|\infty<\infty \hbox{ and } \Big|\partial_y^k{W}y f \Big|{L^\infty(^{n})}\leq C\alpha y^{-k+\alpha/2},;: , {\rm with }, k=[\alpha/2]+1, y>0. \end{equation*} We prove that for , $\Lambda^\alpha_{} = \Lambda_{\alpha/2}^{{W}}.$ As application, we obtain regularity properties of fractional powers (positive and negative) of the operator , Schr"odinger Riesz transforms, Bessel potentials and multipliers of Laplace transforms type. The proofs of these results need in an essential way the language of semigroups. Parallel results are obtained for the classes defined through the Poisson semigroup,

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