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We give the complete classification of all sub-Riemannian model spaces with both step and rank three. They will be divided into three families based on their nilpotentization. Each family will depend on a different number of parameters, making the result crucially different from the known case of step two model spaces. In particular, there are no nontrivial sub-Riemannian model spaces of step and rank three with free nilpotentization. We also realize both the compact real form and the split real form of the exceptional Lie algebra as isometry algebras of different model spaces.

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