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We study the following nonlinear Hartree-type equation \begin{equation*} -\Delta u+V(x)u-a(\frac{1}{|x|^\gamma}\ast |u|^2)u=\lambda u,~~^N, \end{equation*} where , , and is an external potential. We first study the asymptotic behavior of the ground state of equation for , and as . Then we consider the case of some trapping potential , and show that all the mass of ground states concentrate at a global minimum point of as , which leads to symmetry breaking. Moreover, the concentration rate for maximum points of ground states will be given.

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