The spectrum of heavy-hadron molecules is constrained by heavy-quark symmetry in its different manifestations. Heavy-quark spin symmetry for instance connects the properties of the ground and excited states of heavy hadrons, while heavy-antiquark-diquark symmetry connects the properties of heavy antimesons (, ) and doubly heavy baryons (, ). A prediction of these symmetries is that if the is indeed a bound state, then there should be a series of , , , $\Xi_{cc} \Sigma_c^\Xi_{cc}^ \Sigma_c^$ partners. The concrete application of heavy-quark spin symmetry indicates that, if the is a molecule, the existence of a partner with similar binding energy — which we call , given its expected mass — is likely. Conversely, the application of heavy-antiquark-diquark symmetry indicates that the , , $\Xi_{cc}^ \Sigma_c3^+$ molecules are likely to bind too, with binding energies in the range.

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