We present the first results of an ALMA survey of the lower fine structure line of atomic carbon [C I] in far infrared-selected galaxies on the main sequence at in the COSMOS field. We compare our sample with a comprehensive compilation of data available in the literature for local and high-redshift starbursting systems and quasars. We show that the C I luminosity correlates on global scales with the infrared luminosity similarly to low- CO transitions. We report a systematic variation of / as a function of the galaxy type, with the ratio being larger for main-sequence galaxies than for starbursts and sub-millimeter galaxies at fixed . The / and $M_{\rm{[C I]}}M_{\rm dust}$ mass ratios are similar for main-sequence galaxies and for local and high-redshift starbursts within a 0.2 dex intrinsic scatter, suggesting that [C I] is a good tracer of molecular gas mass as CO and dust. We derive a fraction of % of the total carbon mass in the atomic neutral phase. Moreover, we estimate the neutral atomic carbon abundance, the fundamental ingredient to calibrate [C I] as a gas tracer, by comparing and available gas masses from CO lines and dust emission. We find lower [C I] abundances in main-sequence galaxies than in starbursting systems and sub-millimeter galaxies, as a consequence of the canonical and gas-to-dust conversion factors. This argues against the application to different galaxy populations of a universal standard [C I] abundance derived from highly biased samples.

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