A proposal on determination of the effective electro-weak mixing angle ${\rm sin^2\theta_{eff}^f;(f=c,b)}e^+e^-$ collider designed with the possible highest luminosity and running around the center mass energy ) is proposed. It is to determine how the effective mixing angles depend on the flavors, especially the flavors , (with the determined effective ones, the electro-weak mixing angles ${\rm sin^2\theta_W^f;(f=c,b)}$ of Standard Model can be derived out precisely). The key point of the proposal is that at such a super Z-factory, via measuring the forward-backward (), left-right () and combined left-right forward-backward () asymmetries of the produced doubly heavy-flavored hadrons (such as , and the baryons : , and etc) in the relevant production processes and one may complement the final determination of the mixing angle of Standard Model. The advantage of the proposed way to determine the effective electro-weak mixing angles is that the doubly heavy flavor(s) and the out-going direction of the produced doubly-heavy hadron can be experimental determined precisely, i.e. there are no such errors caused by missing identification of the heavy flavor(s) and by determining the so-called thrust axis of the produced jets, which can not be avoided in the early determination at LEP-I and SLC.

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