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In this paper, the definition of Hom-Lie groups is given and one conntected component of Lie group , which is not a subgroup of , is a Hom-Lie group. More, we proved that there is a one-to-one relationship between Hom-Lie groups and Hom-Lie algebras . Next, we also proved that if there is a Hom-Lie group homomorphism, then, there is a morphism between their Hom-Lie algebras. Last, as an application, we use these results on Toda lattice equation.

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