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We investigate the algebraic structure of complex Lie groups equipped with left-invariant metrics which are expanding semi-algebraic solitons to the Hermitian curvature flow (HCF). We show that the Lie algebras of such Lie groups decompose in the semidirect product of a reductive Lie subalgebra with their nilradicals. Furthermore, we give a structural result concerning expanding semi-algebraic solitons on complex Lie groups. It turns out that the restriction of the soliton metric to the nilradical is also an expanding algebraic soliton and we explain how to construct expanding solitons on complex Lie groups starting from expanding solitons on their nilradicals.

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