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In this paper, dual-complex k-Pell numbers and dual-complex k-Pell quaternions are defined. Also, some algebraic properties of dual-complex k-Pell numbers and quaternions which are connected with dual-complex numbers and k-Pell numbers are investigated. Furthermore, the Honsberger identity, the d’Ocagne’s identity, Binet’s formula, Cassini’s identity, Catalan’s identity for these quaternions are given.

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