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We present a detailed spectroscopic investigation of a thermal Rb atomic vapour in magnetic fields up to 0.4T in the Voigt geometry. We fit experimental spectra with our theoretical model and find excellent quantitative agreement, with RMS errors of %. We extract the magnetic field strength and the angle between the polarisation of the light and the magnetic field from the atomic signal and find excellent agreement to within % with a commercial Hall probe. Finally, we present an investigation of the relative sensitivity of this technique to variations in the field strength and angle with a view to enabling atom-based high-field vector magnetometry.

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