In the sealed-off cesium vapor cell studied in this work, a residual rubidium fraction of approximately 1% was observed. We investigate the optical response of these trace Rb atoms in a sealed 1~cm long Cs-filled vapor cell. Despite the low concentration, laser excitation at 795~nm allows the observation of saturated absorption and electromagnetically induced transparency (EIT) resonances. The surrounding Cs vapor effectively acts as a buffer medium, reducing the Rb atomic velocity and increasing the interaction time with the laser field, which improves the EIT signal. The experiments are performed in an all-sapphire cell that can be heated up to 500C without window blackening, unlike conventional glass cells. From the measured spectra, Cs–Rb collisional cross sections are estimated. These results show that residual atomic species in high-temperature vapor cells can be exploited for spectroscopic and nonlinear-optical studies.

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