This paper further investigates \emph{Laplacian simplices}. A construction by Braun and the first author associates to a simple connected graph a simplex whose vertices are the rows of the Laplacian matrix of . In this paper we associate to a reflexive a duality-preserving linear code . This new perspective allows us to build upon previous results relating graphical properties of to properties of the polytope . In particular, we make progress towards a graphical characterization of reflexive using techniques from Ehrhart theory. We provide a systematic investigation of for cycles, complete graphs, and graphs with a prime number of vertices. We construct an asymptotically good family of MDS codes. In addition, we show that any rational rate is achievable by such construction.

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