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In this article, we study the doubly heavy baryon states and pentaquark states with the QCD sum rules by carrying out the operator product expansion up to the vacuum condensates of dimension and respectively in a consistent way. In calculations, we separate the contributions of the negative parity and positive parity hadron states unambiguously, and study the masses and pole residues of the doubly heavy baryon states and pentaquark states in details. The present predictions can be confronted to the experimental data in the future.

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