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We study the exchange of energy between the modes of the optical branch and those of the acoustic one in a diatomic chain of particles, with masses and . We prove that, at small temperature and provided , for the majority of the initial data the energy of each branch is approximately constant for times of order , where $S=\lfloor \sqrt{m_1/m_2}/2\rfloor\beta$ is the inverse temperature. The result is uniform in the thermodynamic limit.

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