Temperature dependence of NMR Knight shift in pnictides: proximity to a van Hove singularity

The unconventional temperature variation of the Knight shift (static spin susceptibility) that has been observed in Fe-based superconductors AFe${}_2$As${}_2$ (A = K, Rb, Cs) is explained in terms of proximity to a van Hove singularity. Using the Hubbard model we show that when the Fermi energy is in the vicinity of a van Hove singularity, a downturn in spin susceptibility occurs as the temperature is lowered. This behavior is characterized by a temperature, $T^{\ast }$, which is determined by the difference in energy between the Fermi level and the van Hove singularity. When vertex corrections are taken into account in a dynamical mean-field approximation, the effect of correlations amplifies the relative drop in the Knight shift and moves $T^{\ast }$ to lower temperatures.