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Within the framework of the perturbative QCD approach, we calculate the time-like form factors and . We include relativistic corrections and QCD corrections, either of which can give about correction to the leading-order contribution, but there are cancellation effects between them. We calculate the cross sections of the $e^+e^-\to B_c^-B_c^+(B_c^{*+})Z\sigma^{PP}(Q=m_Z) \sim 1.3\times10^{-5}\sigma^{PV}(Q=m_Z) \sim 2.5\times10^{-5}$, which are still too small to be detected by proposed colliders such as the Circular Electron Positron Collider.

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