We study the ergodic properties of a class of measures on for which $\mu_{,t}[x_{0}\cdots x_{n-1}]\approx e^{-nP}\left |A_{x_{0}}\cdots A_{x_{n-1}}\right | ^{t}$, where is a collection of matrices. The measure is called a matrix Gibbs state. In particular we give a sufficient condition for a matrix Gibbs state to have the weak Bernoulli property. We employ a number of techniques to understand these measures including a novel approach based on Perron-Frobenius theory. We find that when is an even integer the ergodic properties of are readily deduced from finite dimensional Perron-Frobenius theory. We then consider an extension of this method to using operators on an infinite dimensional space. Finally we use a general result of Bradley to prove the main theorem.

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