Our understanding of the early Universe has long been limited by biased galaxy samples selected through various color criteria. With deep JWST infrared imaging, mass-complete galaxy samples can now be studied up to for the first time. However, recent work has revealed systematic uncertainties in measuring physical properties of galaxies based solely on JWST/NIRCam and HST photometry, due to their limited wavelength coverage. This highlights the need for supplementary data, particularly in the rest-frame UV and near-infrared. Here we present the ULTIMATE-deblending project, which will eventually deliver self-consistent UV-to-Radio photometry for galaxies detected in deep JWST surveys, including both NIRCam and MIRI data. In this first paper, we release a 50-band photometric catalog spanning CFHT/U to JWST/MIRI F1800W, covering a total of 627.1 arcmin across two JWST/PRIMER fields. We detail the reduction of JWST imaging data, the photometric procedures, and the SED-fitting methodology used to derive galaxy properties. Compared with photometry including only HST and JWST bands, the inclusion of deblended low-resolution photometry from ground-based telescopes improves the accuracy of photometric redshifts by 40%, while reducing the outlier fraction by 60%. This galaxy sample can serve as a key reference for statistical studies of galaxy formation and evolution in the early universe. The UV-to-MIR catalogs and JWST mosaics from the ULTIMATE-deblending project have been made publicly available.

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