We report the first detection of the second-forbidden, non-unique, , ground-state transition in the decay of F. A low-energy, mass-separated beam produced at the IGISOL facility in Jyv"askyl"a, Finland, was implanted in a thin carbon foil and the spectrum measured using a magnetic transporter and a plastic-scintillator detector. The -decay branching ratio inferred from the measurement is $b_{\beta} = [ 0.41\pm 0.08\pm 0.07] \times 10^{-5}\log ft = 10.89(11)$, making this one of the strongest second-forbidden, non-unique transitions ever measured. The experimental result is supported by shell-model calculations and has significant implications for the final evolution of stars that develop degenerate oxygen-neon cores. Using the new experimental data, we argue that the astrophysical electron-capture rate on Ne is now known to within better than 25% at the relevant temperatures and densities.

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