Let be a variable exponent function satisfying the globally log-H"older continuous condition and a one to one operator of type in , with , which has a bounded holomorphic functional calculus and satisfies the Davies-Gaffney estimates. In this article, the authors introduce the variable weak Hardy space associated with via the corresponding square function. Its molecular characterization is then established by means of the atomic decomposition of the variable weak tent space which is also obtained in this article. In particular, when is non-negative and self-adjoint, the authors obtain the atomic characterization of . As an application of the molecular characterization, when is the second-order divergence form elliptic operator with complex bounded measurable coefficient, the authors prove that the associated Riesz transform is bounded from to the variable weak Hardy space . Moreover, when is non-negative and self-adjoint with the kernels of satisfying the Gauss upper bound estimates, the atomic characterization of $W!H_L^{p(\cdot)}(\mathbb R^n)$ is further used to characterize the space via non-tangential maximal functions.

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