A positive linear operator between two unital -algebras, with point separating order duals, and is called a Markov operator for which $% T\left( e_{1}\right) =e_{2}e_{1},e_{2}ABABf$-algebras with point separating order duals such that their second order duals and are unital -algebras. In this case, we will call a positive linear operator \ to be a Pre-Markov operator, if the second adjoint operator of is a Markov operator. A positive linear operator between two semiprime -algebras, with point separating order duals, and is said to be contractive if whenever , where and are the identity operators on and respectively. In this paper we characterize pre-Markov algebra homomorphisms. In this regard, we show that a pre-Markov operator is an algebra homomorphism if and only if its second adjoint operator is an extreme point in the collection of all Markov operators from to . Moreover we characterize extreme points of contractive mappings from to . In addition, we give a condition that makes an order bounded algebra homomorphism is a lattice homomorphism.

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