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Adopting the one-boson-exchange model, we perform a systematic investigation of interactions between a doubly charmed baryon and an -wave charmed baryon (, , and ). Both the - mixing effect and coupled-channel effect are considered in this work. Our results suggest that there may exist several possible triple-charm deuteron-like hexaquarks. Meanwhile, we further study the interactions between a doubly charmed baryon and an -wave anticharmed baryon. We find that a doubly charmed baryon and an -wave anticharmed baryon can be easily bound together to form shallow molecular hexaquarks. These heavy flavor hexaquarks predicted here can be accessible at future experiment like LHCb.

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