We study the large-time behavior of the continuous-time heat kernel and of solutions to the heat equation on homogeneous trees. First, we derive sharp asymptotic formulas for the heat kernel as . Second, using them, we show that solutions with initial data in weighted classes, asymptotically factorize in norms, , as the product of the heat kernel, times a -mass function, dependent on the initial condition and . The -mass function is described in terms of boundary averages associated with Busemann functions for , while for , it is expressed through convolution with the ground spherical function. For comparison, the case of the integers shows that a single constant mass determines the asymptotics of solutions to the heat equation for all , emphasizing the influence of the graph geometry on heat diffusion.

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