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We explore the spin states in the quantum spin chain compound SrCoVO up to 14.9 T and down to 50 mK, using single-crystal neutron diffraction. Upon cooling in zero-field, antiferromagnetic (AFM) order of N'eel type develops at 5.0 K. Applying an external magnetic field ( -axis) destabilizes the N'eel order, leading to an order-disorder transition when applying a field between and 1.5 K. Below 1.5 K, we observe a N'eel to longitudinal spin density wave (LSDW) order transition at 3.9 T, and a LSDW to emergent AFM order transition at 7.0 T. Our results also reveal several unique signatures for the states of the spins that are not present in the isostructural counterpart BaCoVO.

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