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We study the and $B_c^- \to \pi^- D^* \bar{D}^*$ reactions and show that they are related by the presence of two resonances, the and , that are of molecular nature and couple most strongly to , but also to . Because of that, in the mass distribution we find a cusp with large strength at the threshold and predict the ratio of strengths between the peak of the cusp and the maximum of the distribution close to threshold, which are distinct features of the molecular nature of these two resonances.

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