We make a detailed study on the meson longitudinal leading-twist distribution amplitude by using the QCD sum rules within the background field theory. By keeping all the non-perturbative condensates up to dimension-six, we obtain accurate QCD sum rules for the moments . The first three ones are , and , leading to a single peaked behavior for which is sharper than the previous ones around the region of . As an application, we adopt the QCD light-cone sum rules to calculate the meson semileptonic decay $B_c^+ \to J/\psi \ell^+ \nu_\ell\Gamma(B_c^+ \to J/\psi \ell^+ \nu_\ell) = (89.67^{+24.76}{-19.06}) \times 10^{-15}~{\rm GeV}\Re(J/\psi \ell^+ \nu\ell) = 0.217^{+0.069}_{-0.057}$, which agree with the next-to-leading order pQCD prediction and the new CDF measurement within errors.

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