The present study is devoted to the possibility that tri-atomic molecules were formed during or shortly after the Big Bang. For this purpose we consider the ordinary and and the primitive tri-atomic molecular system, , which, as is shown, behaves differently. The study is carried out by comparing the topological features of these systems as they are reflected through their non-adiabatic coupling terms. Although the is not known to exist as a molecule, we found that it behaves as such at intermediate distances. However this illusion breaks down as its asymptotic region is reached. Our study indicates that whereas and dissociate smoothly, the , does not seem to do so. Nevertheless, the fact that is capable of living as a molecule on borrowed time enables it to catch an electron and form a molecule via the reaction $H_3^{++} + e \to H_3^{+}H_3^{+} \to H^{+} + H_2H + H_2^+H_3^{++}$ namely, that it is the most primitive system formed by three protons and one electron and topologically, still remain for an instant a molecule, may make it the sole candidate for becoming the \bold{cornerstone} for creating the molecules.

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