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We consider Smoluchowski’s coagulation equation in the case of the diagonal kernel with homogeneity . In this case the phenomenon of gelation occurs and solutions lose mass at some finite time. The problem of the existence of self-similar solutions involves a free parameter , and one expects that a physically relevant solution (i.e. nonnegative and with sufficiently fast decay at infinity) exists for a single value of , depending on the homogeneity . We prove this picture rigorously for large values of . In the general case, we discuss in detail the behaviour of solutions to the self-similar equation as the parameter changes.

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