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We systematically study quantum effect on chiral and symmetry breaking under external electromagnetic fields in the frame of equal-time Wigner function formalism. We derive the transport and constraint equations for the quark distribution functions and the chiral and pion condensates in a Nambu–Jona-Lasinio model. By taking semi-classical expansion of the equations, chiral symmetry is broken at classical level, while symmetry breaking happens only at quantum level. Beyond quasi-particle approximation, the quark off-shell effect leads to strong oscillation for the chiral and pion condensates.

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