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We study the -wave bound state in the Bethe-Salpeter formalism in the ladder and instantaneous approximations. With the kernel generated by the hadronic effective Lagrangian, two open-charmed bound states, which quantum numbers are , and , , respectively, are predicted as new candidates of hadronic pentaquark molecules in our formalism. If existing, they could contribute to the broad 3188 eV structure near the five new narrow states observed recently by the LHCb Collaboration.

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