Let be a Lie group of even dimension and let be a left invariant anti-K"ahler structure on . In this article we study anti-K"{a}hler structures considering the distinguished cases where the complex structure is abelian or bi-invariant. We find that if admits a left invariant anti-K"ahler structure where is abelian then the Lie algebra of is unimodular and is a flat pseudo-Riemannian manifold. For the second case, we see that for any left invariant metric for which is an anti-isometry we obtain that the triple is an anti-K"ahler manifold. Besides, given a left invariant anti-Hermitian structure on we associate a covariant -tensor on its Lie algebra and prove that such structure is anti-K"ahler if and only if is a skew-symmetric and pure tensor. From this tensor we classify the real 4-dimensional Lie algebras for which the corresponding Lie group has a left invariant anti-K"ahler structure and study the moduli spaces of such structures (up to group isomorphisms that preserve the anti-K"ahler structures).

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