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When dilute charged particles are confined in a bounded domain, boundary effects are crucial in the global dynamics. We construct a unique global-in-time solution to the Vlasov-Poisson-Boltzmann system in convex domains with the diffuse boundary condition. The construction is based on an - framework with a novel \textit{nonlinear-normed energy estimate} of a distribution function in weighted -spaces and a -estimate of the self-consistent electric potential. Moreover we prove an exponential convergence of the distribution function toward the global Maxwellian.

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