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We report on photoassociation (PA) spectroscopy of a degenerate Fermi gas of Yb atoms near the dissociation limit of the spin-forbidden intercombination transition. An atom-loss spectrum is measured from a trapped sample for a spectral range down to ~GHz with respect to the atomic resonance. The spectrum shows eighty PA resonances, revealing the high nuclear spin nature of the system. We investigate the Zeeman effect on the spectrum near a detuning of ~GHz, where we examine the quantum numbers of the Zeeman levels using various two-component spin mixture samples. Finally, we measure the atom loss rate under PA light for several pronounced PA resonances.

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