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The asymptotic log-Harnack inequality is established for several different models of stochastic differential systems with infinite memory: non-degenerate SDEs, Neutral SDEs, semi-linear SPDEs, and stochastic Hamiltonian systems. As applications, the following properties are derived for the associated segment Markov semigroups: asymptotic heat kernel estimate; uniqueness of the invariant probability measure; asymptotic gradient estimate and hence, asymptotically strong Feller property; and asymptotic irreducibilty.

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